Submissions
A collection of information used to analyze, calculate, or research a specific topic.
Tools
Software used to analyze, calculate, or research a specific topic.
Presentations
An organized collection of images, graphics, and text used to explain a topic.
Publications
An article that has been printed and made available to the public.

A preliminary investigation of acid-catalyzed polymerization reactions of shale oil distillates

License(s):
Other (Open)

Sinor (1989) reported that a major specialty market may exist for shale oil as an asphalt blending material. Shale oil can be converted to an asphalt blending material by acid catalyzed condensation and polymerization reactions of the many molecular species comprising the composition of shale oil. To simplify the investigation, crude shale oil was separated by distillation into three distillates of different hydrocarbon and heteroaromatic compositions. These distillates were then treated with two different types of acids to determine the effect of acid type on the end products. Three western shale oil distillates, a naphtha, a middle distillate, and an atmospheric gas oil, were reacted with anhydrous AlCl{sub 3} and 85% H{sub 2}SO{sub 4} under low-severity conditions. At relatively low temperatures, little change in the hydrocarbon composition was noted for the AlCl{sub 3} reactions. AlCl{sub 3}{center dot} (a polymerized product and/or complex) was formed. However, it is assumed that the sludge was mainly the result of heteroaromatic-AlCl{sub 3} reactions.


Keywords:
kmd

Data and Resources


    html
    http://www.osti.gov/energycitations/product.biblio.jsp?osti_id=5719827
    No description for this resource
    Other (Open)

Similar Submissions

Additional Info

Field Value
State active
Citation Netzel, D.A.
Is NETL associated Yes
NETL Point of Contact Roy Long
NETL Point of Contact's Email Roy.long@netl.doe.gov
NETL program or project KMD
Publication Date 4/1/1991