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Optical-Cell Evidence for Superheated Ice under Gas-Hydrate-Forming Conditions

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We previously reported indirect but compelling evidence that fine-grained H2O ice under elevated CH4 gas pressure can persist to temperatures well above its ordinary melting point while slowly reacting to form methane clathrate hydrate. This phenomenon has now been visually verified by duplicating these experiments in an optical cell while observing the very slow hydrate-forming process as the reactants were warmed from 250 to 290 K at methane pressures of 23 to 30 MPa.

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Last Updated September 29, 2016, 14:20 (LMT)
Created September 29, 2016, 14:20 (LMT)
Citation Laura A. Stern*, David L. Hogenboom, William B. Durham, Stephen H. Kirby, I-Ming Chou ---- Roy Long, Optical-Cell Evidence for Superheated Ice under Gas-Hydrate-Forming Conditions, 2016-09-29, https://edx.netl.doe.gov/dataset/optical-cell-evidence-for-superheated-ice-under-gas-hydrate-forming-conditions
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1997-12-31