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Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly report, January 1--March 31, 1998

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The last six cycles of a 25-cycle sorbent durability test were completed, final installation of the flame photometric detector was accomplished, and fifteen tests whose aim was to determine the minimum prebreakthrough H{sub 2}S concentration over reduced CeO{sub 2} were performed. There was little, if any, evidence of sorbent deterioration in the durability test. During the durability test the author confirmed that, when using pre-reduced sorbent and a clean system, the prebreakthrough H{sub 2}S concentration was less than 100 ppmv, the detection limit of the thermal conductivity detector (TCD). Consequently, a more sensitive flame photometric detector (FPD) which permitted measurements of H{sub 2}S concentrations of 1 ppmv or less was installed. The FPD and TCD were connected in parallel so that, when desired, the entire H{sub 2}S breakthrough curve could be measured. Most of the quarter was devoted to conducting reduction-sulfidation tests to determine the minimum prebreakthrough H{sub 2}S concentrations which could be achieved using prereduced CeO{sub 2}. Fifteen runs involving variations in reduction-sulfidation temperature, H{sub 2}S concentration in the feed gas, and feed gas volumetric flow rate were completed. In all tests the prebreakthrough H{sub 2}S concentration was less than 10 ppmv, and in many of the tests the H{sub 2}S concentration was equal to or less than 1 ppmv for an extended time period.

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Last Updated September 29, 2016, 15:38 (EST)
Created September 29, 2016, 15:38 (EST)
Citation Harrison, D.P. ---- Roy Long, Advanced sulfur control concepts in hot-gas desulfurization technology. Quarterly report, January 1--March 31, 1998, 2016-09-29, https://edx.netl.doe.gov/dataset/advanced-sulfur-control-concepts-in-hot-gas-desulfurization-technology-quarterly-report-january-10
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1998-8-1