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CARBOXYLIC ACIDS FROM THE TREATMENT OF GREEN RIVER OIL SHALE WITH CARBON MONOXIDE AND WATER

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"The carboxylic acid produced from the reaction of Green River oil shale kerogen with carbon monoxide and water at temperatures of 300- 450°C were investigated. The acid were eterifled with diazomethane, and the acid esters were separated by chromatographic techniques into two fraction : -n-saturated and branched-plus-cyclic saturated acid ester fractions, Gas chromatography (GC) and gas chromatography-ma 's spectrometry (GC-M ) analyses of the n-saturated fractions showed the presence of carboxylic acids of CI4 to C)4 chain length. and the even odd predominance (EO?) was high in fractions produced below 450° C. Isoprenoid saturated acid and terpenoid saturated acid compounds in the branched-plus -cyclic saturated acid fraction predominated at 300°C but decreased tremendously at 450° C. The results of this study show that structures containing carboxyl groups are major components of Green River oil shale kerogen ."

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Last Updated September 29, 2016, 21:25 (LMT)
Created September 29, 2016, 21:25 (LMT)
Citation T.F.Yen, F. K. Kawahara, R. Hertzberg ---- Roy Long, CARBOXYLIC ACIDS FROM THE TREATMENT OF GREEN RIVER OIL SHALE WITH CARBON MONOXIDE AND WATER, 2016-09-29, https://edx.netl.doe.gov/dataset/carboxylic-acids-from-the-treatment-of-green-river-oil-shale-with-carbon-monoxide-and-water
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1983-1-1