Western Research Institute conducted a study to define the various parameters that need to be considered in the design and use of a downhole submersible photoionization detector (PID) probe to measure volatile organic compounds (VOCs). Detector response under various conditions, including saturated humidity environments, temperature, and analyte concentration was studied. The relative responses for several VOC analytes were measured. The partitioning of VOCs between water and air was studied as a function of analyte concentration and temperature. The Henrys law constant governing this partitioning represents an ideal condition at infinite dilution for a particular temperature. The results show that this partitioning is not ideal. Conditions resulting in apparent, practical deviations from Henrys law include temperature and VOC concentration. Studies with membranes show that membranes that allow passage of VOCs also allow some passage of water vapor. A membrane could play a useful role in protecting the sensor from direct contact with liquid water down hole. A porous poly(tetrafluoroethylene) (PTFE) membrane allows for a rapid passage of VOCs. The rate of diffusion to the sensor with or without a membrane might be a limiting factor for rapid measurements. Various means of mixing may need to be considered.