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Chemistry of shale oil cracking

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Results for thermal cracking of shale oil vapor over shale are presented. Cracking temperatures of 504 to 610/sup 0/C and residence times of 2 to 11 seconds were studied. A first-order Arrhenius rate expression and associated stoichiometry were given. Changes in oil properties caused by thermal cracking are also discussed. Cracking increases nitrogen content and decreased the H/C ratio and pour point of the recovered oil. Spectroscopic evidence related the decrease in H/C ratio to an increase in aromatic and alkene content of the oil. Gas-phase oil cracking was contrasted to liquid-phase oil coking as a loss mechanism in oil shale retorting. Results for oils prepared in the laboratory were also compared with oil prepared in the TOSCO-II semi-works and in modified and true in-situ combustion retorts. It was demonstrated that the naphthalene/2-methylnaphthalene ratio is a good indictor of cracking temperature in an oil shale retort.

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Last Updated September 29, 2016, 19:31 (LMT)
Created September 29, 2016, 19:31 (LMT)
Citation Burnham, A.K. ---- Roy Long, Chemistry of shale oil cracking, 2016-09-29, https://edx.netl.doe.gov/dataset/chemistry-of-shale-oil-cracking
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1980-11-26