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Corrosion due to use of carbon dioxide for enhanced oil recovery. Final report. SumX No. 78-003

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This study documents the specific effects of CO/sub 2/ on corrosion and identifies promising methods for controlling corrosion in fields using CO/sub 2/ injection. Information has been assembled on: CO/sub 2/ corrosion problems in general, surface and downhole corrosion problems specifically associated with CO/sub 2/ enhanced oil recovery, and methods to reduce corrosion problems in CO/sub 2/ environments. Corrosion mechanisms, kinetic behavior, and the effects of various parameters on corrosion by CO/sub 2/ are presented in this study. Engineering metals are not attacked by CO/sub 2/ under oil field environments unless liquid water is also present. Plain and low alloy steels are attacked by mixtures of CO/sub 2/ and liquid water. Attack on these bare metals may become serious at a CO/sub 2/ partial pressure as low as 4 psi and it increases with CO/sub 2/ partial pressure although not in direct proportion. Fluid flow rate is an important factor in CO/sub 2//water corrosion. Practically all stainless steels and similar resistant alloys are not particularly subject to corrosion by CO/sub 2//water mixtures alone, even at high CO/sub 2/ pressures. Elevated levels of CO/sub 2/ can aggravate the corrosive effects of other species such as hydrogen sulfide, oxygen, and chloride. Mixtures of CO/sub 2/, carbon monoxide (CO), and water can cause stress corrosion cracking of plain steels. Corrosion problems in CO/sub 2/ systems should be circumvented when possible by avoiding combination of the corrosive components. Although water cannot be excluded throughout the CO/sub 2/ injection-oil production-CO/sub 2/ and water reinjection chain, air in-leakage can be minimized and oxygen scavengers used to remove any residual. Exclusion of oxygen is important to the successful use of other corrosion control measures. A discussion is given of the main control methods including metal selection, protective coatings and nonmetallic materials, and chemical inhibition. (DLC)

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Last Updated September 29, 2016, 16:04 (LMT)
Created September 29, 2016, 16:04 (LMT)
Citation DeBerry, D.W.; Clark, W.S. ---- Roy Long, Corrosion due to use of carbon dioxide for enhanced oil recovery. Final report. SumX No. 78-003, 2016-09-29, https://edx.netl.doe.gov/dataset/corrosion-due-to-use-of-carbon-dioxide-for-enhanced-oil-recovery-final-report-sumx-no-78-003
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1979-9-1