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Corrosion resistant materials in MCFC (molten carbonate fuel cell) environment: Final report, October 1984-September 1986. [Current collector/bipolar plate]

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This report describes a 24-month effort in the development of a corrosion resistant hardware material for molten carbonate fuel cell (MFC) application. The objective of this program was to identify an inexpensive alloy for MCFC current collector/bipolar plate application. For this work, 310S was selected as the base alloy composition and La, Ce and Si were added to improve corrosion resistance. Eight candidate alloys, including 310S and 316L, were screened in MCFC anode and cathode atmospheres. The techniques used include isothermal corrosion, acoustic emission, thermal cycling corrosion, thermogravimetric analyses, electrical surface resistance, and dual atmosphere corrosion testing. Oxide scales formed were analyzed by standard metallographic techniques. The results indicate that COLT-25 and Crutemp-25 alloys (both containing 25Cr-25Ni and balance Fe) have the best corrosion resistance in the MCFC environment. Rare earth additives, La and Ce, do not appear to improve isothermal or thermal cycling resistance a great deal. Silicon addition appears to improve thermal cycling but not isothermal corrosion resistance. High Mn content (approx.18%) appears detrimental based on this limited investigation. Currently used 316L has the least corrosion resistance of all the alloys tested. Pressurized tests have shown that high pressure (10 atm) reduces corrosion rate in the anode atmosphere whereas it only slightly affects corrosion rate in the cathode atmosphere. 37 refs., 47 figs., 12 tabs.

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Last Updated September 29, 2016, 16:36 (LMT)
Created September 29, 2016, 16:36 (LMT)
Citation Pigeaud, A.; Yuh, C.Y.; Singh, P. ---- Roy Long, Corrosion resistant materials in MCFC (molten carbonate fuel cell) environment: Final report, October 1984-September 1986. [Current collector/bipolar plate], 2016-09-29, https://edx.netl.doe.gov/dataset/corrosion-resistant-materials-in-mcfc-molten-carbonate-fuel-cell-environment-final-report-octob
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1986-1-1