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Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

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CRS Sirrine (CRSS) is evaluating a novel IGCC process in which gases exiting the gasifier are burned in a gas turbine combustion system. The turbine exhaust gas is used to generate additional power in a conventional steam generator. This results in a significant increase in efficiency. However, the IGCC process requires development of novel approaches to control SO{sub 2} and NO{sub x} emissions and alkali vapors which can damage downstream turbine components. Ammonia is produced from the reaction of coal-bound nitrogen with steam in the reducing zone of any fixed bed coal gasifier. This ammonia can be partially oxidized to NO{sub x} when the product gas is oxidized in a gas turbine combustor. Alkali metals vaporize in the high-temperature combustion zone of the gasifier and laser condense on the surface of small char or ash particles or on cooled metal surfaces. It these alkali-coated materials reach the gas turbine combustor, the alkali will revaporize condense on turbine blades and cause rapid high temperature corrosion. Efficiency reduction will result. PSI Technology Company (PSIT) was contracted by CRSS to evaluate and recommend solutions for NO{sub x} emissions and for alkali metals deposition. Various methods for NO{sub x} emission control and the potential process and economic impacts were evaluated. This included estimates of process performance, heat and mass balances around the combustion and heat transfer units and a preliminary economic evaluation. The potential for alkali metal vaporization and condensation at various points in the system was also estimated. Several control processes and evaluated, including an order of magnitude cost for the control process.

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Last Updated September 29, 2016, 16:02 (LMT)
Created September 29, 2016, 16:02 (LMT)
Citation Roy Long, Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems, 2016-09-29, https://edx.netl.doe.gov/dataset/development-of-standardized-air-blown-coal-gasifier-gas-turbine-concepts-for-future-electric-powe0
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1990-7-1