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Hydrodenitrification of crude shale oil. [Hydrogenation at 685 to 800/sup 0/F, 600 to 1400 psig]

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Crude shale oil was hydrogenated over a cobalt molybdate-on-alumina catalyst at temperatures of 685, 740, and 800 degrees F; pressures of 600, 1,000, and 1,400 psig; and liquid hourly space velocities of 0.1, 0.15, and 0.3. Hydrogen consumption ranged from 870 to 2,010 scf/bbl and increased exponentially with the degree of denitrification or amount of nitrogen removed. Nitrogen compound types in the crude shale oil and the hydrotreated products were determined by a combination of infrared spectrometry and nonaqueous potentiometer techniques. Nitrogen contents of the hydrotreated products ranged from 1.59 to 0.005 weight-percent. Hydrogen partial pressure had a significantly greater effect on the denitrification rate constants for insole-type nitrogen compounds than on either quinoline-type nitrogen compounds or total nitrogen. The data show that, while at the temperatures and pressures used the denitrification rate constants for quinoline-type nitrogen compounds were greater than the denitrification rate constants for insole-type nitrogen compounds, at pressures above 3,000 psig the opposite would be true.

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Last Updated September 29, 2016, 17:18 (LMT)
Created September 29, 2016, 17:18 (LMT)
Citation Frost, C.M. Poulson, R.E. ; Jensen, H.B. ---- Roy Long, Hydrodenitrification of crude shale oil. [Hydrogenation at 685 to 800/sup 0/F, 600 to 1400 psig], 2016-09-29, https://edx.netl.doe.gov/dataset/hydrodenitrification-of-crude-shale-oil-hydrogenation-at-685-to-800-sup-0-f-600-to-1400-psig
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1975-7-1