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Low pH alkaline chemical formulations

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This report describes the development of a surfactant-enhanced alkaline flooding system that is applicable to specific reservoir conditions in Wilmington (California) field. The cost of the chemicals for an ASP (alkali/surfactant/polymer) flood is calculated to be $3.90/bbl of oil produced, with 78% of that cost attributable to polymer. This research included phase behavior tests, oil displacement tests, mineral dissolution tests, and adsorption measurements. It was discovered that consumption of low pH alkalis is low enough in the Wilmington field to be acceptable. In addition, alkali dramatically reduced surfactant adsorption and precipitation. A mixture of NaHCO3 and Na2CO3 was recommended for use as a preflush and in the ASP formulation. Research was also conducted on the synergistic effect that occurs when a mixture of alkali and synthetic surfactant contacts crude oil. It appears that very low IFT is predominantly a result of the activation of the natural surfactants present in the Wilmington oil, and the sustained low IFT is primarily the result of the synthetic surfactant. It also appears that removal of acids from the crude oil by the alkali renders the oil more interfacially reactive to synthetic surfactant. These phenomena help to explain the synergism that results from combining alkali and synthetic surfactant into a single oil recovery formulation. 19 refs., 24 figs., 10 tabs.

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Last Updated September 29, 2016, 16:33 (LMT)
Created September 29, 2016, 16:33 (LMT)
Citation French, T.R. Peru, D.A. ; Thornton, S.D. ---- Roy Long, Low pH alkaline chemical formulations, 2016-09-29, https://edx.netl.doe.gov/dataset/low-ph-alkaline-chemical-formulations
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1989-1-1