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MERCURY STABILIZATION IN CHEMICALLY BONDED PHOSPHATE CERAMICS*

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Mercury stabilization and solidification is a significant challenge for conventional stabilization technologies. This is because of the stringent regulatory limits on leaching of its stabilized products. In a conventional cement stabilization process, Hg is converted at high pH to its hydroxide, which is not a very insoluble compound; hence the preferred route for Hg sulfidation to convert it into insoluble cinnabar (HgS). Unfortunately, efficient formation of this compound is pH-dependent. At a high pH, one obtains a more soluble Hg sulfate, in a very low pH range, insufficient immobilization occurs because of the escape of hydrogen sulfide, while efficient formation of HgS occurs only in a moderately acidic region. Thus, the pH range of 4 to 8 is where stabilization with Chemically Bonded Phosphate Ceramics (CBPC) is carried out.

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Last Updated September 29, 2016, 14:31 (LMT)
Created September 29, 2016, 14:31 (LMT)
Citation Arun S. Wagh, Dileep Singh, and Seung-Young Jeong ---- Roy Long, MERCURY STABILIZATION IN CHEMICALLY BONDED PHOSPHATE CERAMICS*, 2016-09-29, https://edx.netl.doe.gov/dataset/mercury-stabilization-in-chemically-bonded-phosphate-ceramics
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 2000-3-1