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Molten carbonate fuel cell performance model update. Quarterly report, October 1983-December 1983

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This report contains a detailed description of a new porous electrode model, termed the heterogeneous film model, which is intended to be a reasonable depiction of ERC's ceramic coated Ni anodes and to serve as a first approximation to GE's and ANL's Ni/Cr anodes. In this model the electrode is pictured as a highly crosslinked three-dimensional network of Ni or Ni/Cr filaments. The Ni or Ni/Cr is coated by a porous layer of ceramic or chromite. Most of the fine-scale porosity of the electrode is found in the layer. Consequently most of the electrolyte resides in this layer which then forms a heterogeneous film on the Ni or Ni/Cr surface. The film coated Ni or Ni/Cr network is idealized as a random packing of short cylinders. The theoretical development of the model includes mathematical descriptions of ionic conduction, liquid phase diffusion through the heterogeneous film, and electrode kinetics on the Ni or Ni/Cr surface. Arguments based on conservation of porosity are used to express the geometric parameters of the model in terms of a few observable properties of the electrode. This report also contains a detailed mathematical analysis of the development of vertical concentration gradients in the gas flow channels. A general solution is presented and applied to the cathode and anode flow channels. Application to the anode requires some modifications due to the occurrence of the water gas shift reaction on the channel hardware surfaces.

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Last Updated September 29, 2016, 16:32 (LMT)
Created September 29, 2016, 16:32 (LMT)
Citation Wilemski, G.; Kemp, N.H. ---- Roy Long, Molten carbonate fuel cell performance model update. Quarterly report, October 1983-December 1983, 2016-09-29, https://edx.netl.doe.gov/dataset/molten-carbonate-fuel-cell-performance-model-update-quarterly-report-october-1983-december-1983
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1984-3-1