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Nitric oxide (NO) reduction by retorted oil shale

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Nitric oxide gas (NO) is effectively reduced by retorted oil shale. At 300/sup 0/C half of the NO in a gas stream is removed when the gas stream contacts a bed of crushed retorted oil shale for 0.4 s. The fraction removed in 0.4 s reaches 90% at a temperature of 375/sup 0/C. As long as the reducing agent, presumed to be char in the retorted shale, is not depleted, the rate of reduction of NO appears to be proportional to the partial pressure of NO, and our results can be expressed in terms of a rate constant (k) which is a function of temperature (T, Kelvin) as follows: k = Ae/sup -//sup E/RT/ (s/sup -1/), where A = 4.0 x 10/sup 5/ (s/sup -1/) and E = 59.7 kJ/mole. This rate is many times faster than the rate of reduction of NO by coal char as measured by Furusawa et al. (1983). The principal reduction reaction is unknown; it does not release CO/sub 2/.

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Last Updated September 29, 2016, 17:18 (LMT)
Created September 29, 2016, 17:18 (LMT)
Citation Taylor, R.W. Morris, C.J. ---- Roy Long, Nitric oxide (NO) reduction by retorted oil shale, 2016-09-29, https://edx.netl.doe.gov/dataset/nitric-oxide-no-reduction-by-retorted-oil-shale
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1983-10-1