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Processing of oil shale in molten hydroxides

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Scoping experiments to determine bounds on a possible process for producing fuel hydrocarbons from oil shale by pyrolysis in a bath of molten Na, Li, and K hydroxides have been done. The process can be carried out at relatively low temperatures, 200 to 225/sup 0/C, requires the presence of water and oxygen, and gives hydrocarbon and organic acid products, apparently free of sulfur and nitrogen. A mechanism of oxidation of kerogen at heteroatoms and other functional groups, followed by decarboxylation of organic acids, is consistent with the observations but is speculative at this time.

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Last Updated September 29, 2016, 18:47 (LMT)
Created September 29, 2016, 18:47 (LMT)
Citation Hues, A.D. Rofer-DePoorter, C.K. ; Rogers, R.N. ---- Roy Long, Processing of oil shale in molten hydroxides, 2016-09-29, https://edx.netl.doe.gov/dataset/processing-of-oil-shale-in-molten-hydroxides
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1984-1-1