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Reaction kinetics for remodeling oil shale retorting

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Results from recent laboratory kinetic studies at the Lawrence Livermore Laboratory (LLL) on gasification, pyrolysis, and mineral reactions in oil shale are presented. The specific pyrolysis reactions investigated include the decomposition of kerogen, the evolution of oil, hydrogen and C/sub 2/ plus C/sub 3/ hydrocarbons and the formation of a carbonaceous residue. Data describing the evolution of H/sub 2/ and CH/sub 4/ during secondary pyrolysis of the carbonaceous residue are also presented. The mineral reaction kinetics discussed include the decomposition and/or reaction (with silica or silicates) of calcite, dolomite, dawsonite and nahcolite. Rate equations describing the effects of CO/sub 2/ and steam on the reactions of calcite and dolomite are presented. Finally, kinetics describing gasification of the carbonaceous residue by CO/sub 2/ and H/sub 2/O are examined. The above kinetic data are summarized in a set of rate expressions that can be used in numerical modeling of oil shale retorting. The rate equations are general enough for modeling both in-situ and surface retorting processes.

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Last Updated September 29, 2016, 18:20 (LMT)
Created September 29, 2016, 18:20 (LMT)
Citation Campbell, J.H. Burnham, A.K. ---- Roy Long, Reaction kinetics for remodeling oil shale retorting, 2016-09-29, https://edx.netl.doe.gov/dataset/reaction-kinetics-for-remodeling-oil-shale-retorting
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1979-1-1