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The effects of halides on the performance of coal gas-fueled molten carbonate fuel cells: Final report, October 1986-October 1987

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This report presents the results of a program to determine the probable tolerable limits of hydrogen chloride and hydrogen fluoride present in the fuel and oxidant streams of molten carbonate fuel cells that are operating on gasified coal. A literature survey and thermodynamic analyses were performed to determine the likely effects of halides on cell performance and materials. Based on the results of these studies, accelerated corrosion experiments and electrode half-cell performance tests were conducted using electrolyte which contained chloride and fluoride. These data and the results of previous in-cell tests were used to develop a computer for predicting the performance decay due to these halides. The tolerable limits were found to be low (less than 1 PPM) and depend on the power plant system configuration, the operating conditions of the fuel cell stack, the cell design and initial electrolyte inventory, and the ability of the cell to scrub low levels of halide from the reactant streams. The primary decay modes were conversion of the electrolyte from pure carbonate to a carbonate-halide mixture and accelerated electrolyte evaporation. 75 figs., 16 tabs.

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Last Updated September 29, 2016, 15:51 (LMT)
Created September 29, 2016, 15:51 (LMT)
Citation Magee, T.P.; Kunz, H.R.; Krasij, M.; Cote, H.A. ---- Roy Long, The effects of halides on the performance of coal gas-fueled molten carbonate fuel cells: Final report, October 1986-October 1987, 2016-09-29, https://edx.netl.doe.gov/dataset/the-effects-of-halides-on-the-performance-of-coal-gas-fueled-molten-carbonate-fuel-cells-final-rep
Netl Product yes
Poc Email Roy.long@netl.doe.gov
Point Of Contact Roy Long
Program Or Project KMD
Publication Date 1987-10-1