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The mobile phase in coals: Its nature and modes of release: Final report: Part 1, Structural inferences from dry catalytic hydrogenation of a subbituminous coal

In a study to provide insight into the two component structural model of coal and the mechanisms of coal liquefaction, an approach was adopted in which a subbituminous coal was reacted with hydrogen in the presence of an impregnated molybdenum sulphide catalyst and in the absence of solvent. Reactions were conducted at temperatures between 300 and 400/sup 0/C and for reaction times up to 180 min. The composition and yields of gaseous products, chloroform-soluble liquids and insoluble residues were followed as a function of the reaction conditions by means of different analytical and characterization techniques: gas chromatography; /sup 1/H NMR; elemental analysis; FTIR; solvent swelling in pyridine. 105 refs., 20 figs., 12 tabs.

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Last Updated July 3, 2014, 15:42 (LMT)
Created July 3, 2014, 15:38 (LMT)
Citation Terrer, M.T., & Derbyshire, F.J. (1986). The mobile phase in coals: Its nature and modes of release: Final report: Part 1, Structural inferences from dry catalytic hydrogenation of a subbituminous coal. doi:10.2172/5665302
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